NGC 6231 (also known as Caldwell 76) is an open cluster in the southern sky located half a degrees north of Zeta Scorpii. NGC 6231 is part of a swath of young, bluish stars in the constellation Scorpius known as the Scorpius OB1 association. The star Zeta1 (HR 6262) is a member of this association, while its brighter apparent partner, Zeta2 (HR 6271), is only 150 ly from Earth and so is not a member.This cluster is estimated about 2–7 million years old, and is approaching the Solar System at 22 km/s. The cluster and association lie in the neighboring Sagittarius Arm of the Milky Way. Zeta1 Scorpii (spectral type O8 and magnitude 4.71.) is the brightest star in the association, and one of the most radiant stars known in the galaxy.NGC 6231 also includes three Wolf-Rayet stars: HD 151932, HD 152270, and HD 152408.

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